First, allow me to join with Knightly in thanking you for your service. For some reason I always find myself with military types; my dad served during the Korean War and during my two summers as a teenaged mate on a charter fishing boat I was regaled with stories from WWII, Korean and Viet Nam vets. My best friend was a tin-can squid, my brother-in-law served on a boomer, and I played for seven years with the Del Vikings, which was started by five Air Force NCOs and throughout the years continued the tradition of its members being vets; another friend served in Iraq. For some reason I have been honored to be told many things that most veterans don't usually talk about. All of you have my utmost respect.
Mono is the way that all dialog is recorded for film and TV, so you're just fine there.
Higher bit rates allow for more headroom (volume before distortion). 16 bit is CD and DVD standard, 24 bit is hi-def.
Higher sample rates, expressed as kilohertz (kHz) allow for more sonic detail. As an audio post guy I prefer high sample rates because I get fewer artifacts when I manipulate the sounds. 44.1 kHz is CD standard, 48 kHz is DVD standard and 96kHz is hi-def.
I find little difference between AIF and WAV. I use BWAV (Broadcast WAV, sometimes called BWF or Broadcast Wave Format), it seems to cross platforms a bit better. So, summing up, I use 24bit/96kHz BWAV when I do audio post.
I'll also echo Knightly in suggesting you get a boom-pole if you can find someone to "swing" it for you. The Rode VideoMic doesn't use XLR, so would not be much use to you at this point, but since the Rode VideoMic is high impedance you should try to keep your cable runs short.