"Sweetening" is not the kind of thing that can be covered in a post.
EQ is used to reduce or eliminate unwanted frequencies, and to enhance others. It is also used to "fit" the myriad pieces of the audio post puzzle into a coherent whole during the mix process. A very basic example is when you "carve a hole" or reduce frequencies in the score that the dialog occupies.
Reverbs are used to create or match the reflective properties of a space, everything from a bathroom to a gymnasium to a canyon. Quite often you use reverb on the Foley and sound FX to match the ambient/reflective properties of the room in which the dialog was recorded.
Dynamic processors (limiters, compressors, expanders and companders) are used to manipulate the dynamic range of everything from individual sound clips to whole tracks to the entire mix.
Before you even get to that point you need to be able to create the proper sounds (Foley and sound FX). This is also a combination of technology and artistry - mic selection and placement, selecting the props used to create the desired sounds, and then "performing" the Foley or sound effect.
Having the proper mixing environment and speakers is a major piece of what is needed, but even more are the years of experience that makes it instinctual.
You can read dozens of books and blogs, and watch endless "how to" videos, but it all comes down to knowledge and experience. It's always amazing how often very subtle changes make such a substantial difference, but you never really catch on until you listen to the an expert at work during the process. I'm not trying to discourage you, I'm just saying that you have to do the job a lot and in the proper environment. I've been doing this for almost ten years now, and recorded and mixed music for quite a few years before that. I'm very good at what I do, but am often humbled when I get to observe (and occasionally work with) one of the masters of the craft. Look at it this way, how many hours have you put into learning how to set up, frame and light a shot? How many times have you done it? How good are you at that? You have to put in an equal amount of time to achieve the same proficiency with the audio post process.
Just for fun, if you want to turn green with envy (as I do on a regular basis) check out the websites for Skywalker Sound, Sony Pictures, Warner Brothers and Disney. Just one of their editing suites is many times the cost of my shop. And the mixing stages; HOLY CRAP!!! There are a number of smaller but equally nice places in the NY metro area, like Nutmeg Audio Post, Creative Audio Post, my buddy Frank Piazzas place Audio Paint/Legal Audio, and Real Recording (where I've worked for my friend Questar) in Manhattan.